(+/-)-cis-dichloro[P-(isopropylamino)-dinaphto[2,1-d:1',2'-f][1,3,2]dioxaphosphepine](triethylphosphine)platinum(II) dichloromethane solvate | 174367-23-8

• 英文名称: (+/-)-cis-dichloro[P-(isopropylamino)-dinaphto[2,1-d:1',2'-f][1,3,2]dioxaphosphepine](triethylphosphine)platinum(II) dichloromethane solvate
• CAS: 174367-23-8
• 化学式: CH₂Cl₂*C₂₉H₃₅Cl₂NO₂P₂Pt
• 分子量: 842.469
• InChiKey: OGQXMIJLALHTIE-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [dichloro(triethylphosphine)platinum(II)]2 、 (isopropylamino)([1,1'-binaphtyl]-2,2'-dioxy)phosphane 以 二氯甲烷 为溶剂， 生成 (+/-)-cis-dichloro[P-(isopropylamino)-dinaphto[2,1-d:1',2'-f][1,3,2]dioxaphosphepine](triethylphosphine)platinum(II) dichloromethane solvate
  参考文献：
  名称：

  (±)-cis-Dichloro[P-(isopropylamino)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine](triethylphosphine)platinum(II) Dichloromethane Solvate

  摘要：

  In the racemic title compound, [PtCl2(C23H20NO2P)-(C6H15P)].CH2Cl2, the platinum(II) ion, which has approximately square-planar coordination geometry, is coordinated to two different monophosphorus ligands in a cis arrangement along with two chloride ions. A significant shortening of the P-N bond [1.604(7) Angstrom] relative to that in phosphinoamines and their complexes was observed.

  DOI：

  10.1107/s010827019500922x