| 156524-61-7

• CAS: 156524-61-7
• 化学式: C₂₂H₄₂ClIrO₆P₂
• 分子量: 692.192
• InChiKey: TWOPBDSNAJMXBM-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  在 H₂O 作用下， 以 二氯甲烷 、 苯 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  Metal-Assisted Cleavage of a C-O Bond of a P-Bound Bifunctional Phosphine Ligand

  摘要：

  Treatment of [IrCl(C2H4)2]2 (1) with the phosphino ester iPr2PCH2CO2Me affords the mononuclear complex trans-[IrCl(C2H4)(Ipr2pch2co2me-kappaP2] (2), which reacts with CO to give trans-[IrCl(CO)(Ipr2pch2co2me-kappaP2] (3) and with HC=CR to give [IrH(C=CR)Cl-(Ipr2pch2co2me-kappaP)(Ipr2pch2co2me-kappa2P,O)] (R = Ph (4), CO2Me (5)). Upon heating, the alkynylhydridoiridium compounds 4 and 5 rearrange to yield the isomeric vinylidenemetal derivatives trans-[IrCl(=C=CHR) (Ipr2pch2co2me-kappaP)2] (R = Ph (6), CO2Me (7)). Reaction of 3, 6, and 7 with Al2O3/H2O leads to cleavage of a CH3-O bond of one phosphino ester ligand and gives the chelate complexes [Ir(L)(Ipr2pch2co2me-kappaP)(iPr2PCH2CO2-kappa2P,O)] (L = CO (8), C=CHPh (9), C=CHCO2Me (10)) in 80-90 % yield. Compound 8 reacts with methyl iodide by oxidative addition to form the octahedral complex [IrI(CH3)(CO)(Ipr2pch2co2me-kappaP)-(Ipr2pch2co2-kappa2P,O)] (11). The X-ray crystal structure of 8 has been determined (triclinic, space group P1BAR (No. 2), with a = 9.124(5) angstrom, b = 11.301(7) angstrom, c = 12.126(6) angstrom, alpha = 79.34(4)degrees, beta = 78.92(4)degrees, gamma = 71.56(5)degrees, and Z = 2).

  DOI：

  10.1021/om00019a025
• 作为产物：
  描述：

  以 苯 为溶剂， 以77%的产率得到
  参考文献：
  名称：

  Metal-Assisted Cleavage of a C-O Bond of a P-Bound Bifunctional Phosphine Ligand

  摘要：

  Treatment of [IrCl(C2H4)2]2 (1) with the phosphino ester iPr2PCH2CO2Me affords the mononuclear complex trans-[IrCl(C2H4)(Ipr2pch2co2me-kappaP2] (2), which reacts with CO to give trans-[IrCl(CO)(Ipr2pch2co2me-kappaP2] (3) and with HC=CR to give [IrH(C=CR)Cl-(Ipr2pch2co2me-kappaP)(Ipr2pch2co2me-kappa2P,O)] (R = Ph (4), CO2Me (5)). Upon heating, the alkynylhydridoiridium compounds 4 and 5 rearrange to yield the isomeric vinylidenemetal derivatives trans-[IrCl(=C=CHR) (Ipr2pch2co2me-kappaP)2] (R = Ph (6), CO2Me (7)). Reaction of 3, 6, and 7 with Al2O3/H2O leads to cleavage of a CH3-O bond of one phosphino ester ligand and gives the chelate complexes [Ir(L)(Ipr2pch2co2me-kappaP)(iPr2PCH2CO2-kappa2P,O)] (L = CO (8), C=CHPh (9), C=CHCO2Me (10)) in 80-90 % yield. Compound 8 reacts with methyl iodide by oxidative addition to form the octahedral complex [IrI(CH3)(CO)(Ipr2pch2co2me-kappaP)-(Ipr2pch2co2-kappa2P,O)] (11). The X-ray crystal structure of 8 has been determined (triclinic, space group P1BAR (No. 2), with a = 9.124(5) angstrom, b = 11.301(7) angstrom, c = 12.126(6) angstrom, alpha = 79.34(4)degrees, beta = 78.92(4)degrees, gamma = 71.56(5)degrees, and Z = 2).

  DOI：

  10.1021/om00019a025