trans-dichlorobis(7-thiabicyclo[2.2.1]heptane)palladium(II) | 164728-03-4

• 英文名称: trans-dichlorobis(7-thiabicyclo[2.2.1]heptane)palladium(II)
• CAS: 164728-03-4
• 化学式: C₁₂H₂₀Cl₂PdS₂
• 分子量: 405.749
• InChiKey: BXKMHZZGBIJESB-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  7-Thia-bicyclo<2.2.1>heptan 、 palladium dichloride 以 乙醇 为溶剂， 生成 trans-dichlorobis(7-thiabicyclo[2.2.1]heptane)palladium(II)
  参考文献：
  名称：

  trans-Dichlorobis(7-thiabicyclo[2.2.1]heptane)palladium(II) and trans-Dichlorobis(7-thiabicyclo[2.2.1]heptane)platinum(II)

  摘要：

  The asymmetric unit of the title Pd complex, [PdCl2(C6H10S)(2)], consists of two independent half molecules lying on inversion centres. The Pd atoms have square-planar coordination with Pd-S distances of 2.300(2) and 2.313(2) Angstrom, Pd-Cl distances of 2.300(2) and 2.307(2) Angstrom, and S-Pd-Cl angles of 88.21(8) and 90.12(8)degrees. The Pt complex, [PtCl2(C6H10S)(2)], has the Pt atom lying on an inversion centre, also has square-planar coordination, and has a Pt-S distance of 2.286(2), a Pt-Cl distance of 2.300(2) Angstrom and a S-Pt-Cl angle of 89.25(8)degrees.

  DOI：

  10.1107/s0108270194014861