di-μ-chloro-bis[chloro(η(5)-indenyl)methylhafnium(IV)] | 216435-02-8

• 英文名称: di-μ-chloro-bis[chloro(η(5)-indenyl)methylhafnium(IV)]
• CAS: 216435-02-8
• 化学式: C₂₀H₂₀Cl₄Hf₂
• 分子量: 759.171
• InChiKey: IQQINURAENHAHZ-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  三甲基铝 、 [(η(5)-C9H7)HfCl2(μ-Cl)]2 以 甲苯 为溶剂， 生成 di-μ-chloro-bis[chloro(η(5)-indenyl)methylhafnium(IV)]
  参考文献：
  名称：

  Di-μ-chloro-bis[chloro(η⁵-indenyl)methylhafnium(IV)]

  摘要：

  The molecular structure of the title complex, [HfCl(mu- Cl)(CH3)(eta(5)-C9H7)](2), which is a rare example of an indenylhafnium alkyl complex, is described. In this centrosymmetric structure, the geometry around each Hf atom is best described as a pseudo-square pyramid. There is a small amount of disorder between the methyl groups and the terminal chloride ligands.

  DOI：

  10.1107/s0108270198005368