| 167286-94-4

• CAS: 167286-94-4
• 化学式: C₂₃H₃₃NSiTi
• 分子量: 399.487
• InChiKey: JRUGQNNGOFNLBK-DURVFHFYSA-N

反应信息

• 作为产物：
  描述：

  dimethylsilanediyl(tetramethylcyclopentadienyl)(phenylamino)titanium dichloride 、 反-1,3-戊二烯 以 正己烷 为溶剂， 生成 、
  参考文献：
  名称：

  Constrained-Geometry Titanium(II) Diene Complexes. Structural Diversity and Olefin Polymerization Activity

  摘要：

  Reduction of (eta(5):eta(1)-C(5)Me(4)SiMe(2)NR)TiCl2 with (n)BuLi in the presence of various 1,3-dienes yields (eta(5):eta(1)-C(5)Me(4)SiMe(2)NR)Ti(diene) complexes. The diene coordination mode (pi formally Ti(II), or metallacyclic, formally Ti(IV)) and the activity for olefin. polymerization (which can be very high) are highly sensitive to the identity of R.

  DOI：

  10.1021/om00007a005