η(5),η(5)-(9,9-bisfluorenylidene)phenylphosphine hafnium dichloride | 215813-00-6

• 英文名称: η(5),η(5)-(9,9-bisfluorenylidene)phenylphosphine hafnium dichloride
• CAS: 215813-00-6
• 化学式: C₃₂H₂₁Cl₂HfP
• 分子量: 685.888
• InChiKey: BGOXFSQKYIIYFX-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  氯化铪 、 bis-(9-fluorenyl)-(phenyl) phosphine 在 正丁基锂 作用下， 以 乙醚 、 正己烷 为溶剂， 生成 η(5),η(5)-(9,9-bisfluorenylidene)phenylphosphine hafnium dichloride
  参考文献：
  名称：

  PPh-bridged metallocene complexes of the type (C13H8–PPh–C13H8)MCl2 (M=Zr, Hf)

  摘要：

  The synthesis and NMR spectroscopic characterization of new ansa-metallocene dichloride complexes of the type (C13H8-PPh-C13H8)MCl2 (M = Zr (5), Hf (6)) is reported. The complexes can be activated with methylaluminoxane (MAO), and are then able to polymerize ethylene. In contrast to CR2 and SiR2 bridged derivatives, the PPh bridge increases the electron density of the system which leads to a drastic decrease in polymerization activities. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00735-9