[(Rh(μ-pyrazolate)(μ-S(t)Bu)(P(OMe)3))2Pd] | 138997-68-9

• 英文名称: [(Rh(μ-pyrazolate)(μ-S(t)Bu)(P(OMe)3))2Pd]
• CAS: 138997-68-9
• 化学式: C₂₂H₄₂N₄O₈P₂PdRh₂S₂
• 分子量: 928.908
• InChiKey: GUGRFUXDGNIVQM-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  [(Rh(μ-pyrazolate)(μ-S(t)Bu)(P(OMe)3))2Pd] 、 碘甲烷 以 二氯甲烷 为溶剂， 以60%的产率得到[(Rh(μ-pyrazolate)(μ-S(t)Bu)I(Me)(CO)(P(OMe)3))2Pd]
  参考文献：
  名称：

  From Methyl to Acetyl Complexes. An Example of Alkyl Migration in Heterotrinuclear Systems. Crystal and Molecular Structure of [{Rh(.mu.-pz)(.mu.-StBu)I(COMe)P(OMe)3}2Pd]

  摘要：

  The addition of methyl iodide to the heterotrinuclear compound [{Rh(mu-pz)(mu-S-t-Bu)(CO)(P(OMe)(3))}Pd-2] leads to the formation of the complex [{Rh(mu-pz)(mu-S(t)Bu)I-(Me)(CO)(P(OMe)(3))}Pd-2] . After 36 h of reaction the spectroscopic data indicate the only presence of the acetyl derivative [{Rh(mu-pz)(mu-S(t)Bu)I(COMe)(P(OMe)(3))}Pd-2] whose structure has been determinated by X-ray diffraction study. The present paper reports a methylation process which deals with a MeOC-Rhm(III)... Pd ... Rh-III-COMe system.[GRAPHICS]t> Rh-III-COMe system.[GRAPHICS]ation of a dimeric entity is achieved by a bridging ClO4 while hydrogen bonds from the imino groups to terminal and bridging ClO4 link two dimers to yield a ''dimer of dimers''.[GRAPHICS]GRAPHICS]

  DOI：

  10.1021/ic00115a046