| 166045-75-6

• CAS: 166045-75-6
• 化学式: C₂₆H₂₆AlClZr
• 分子量: 492.151
• InChiKey: WPOCXWNFMZNCCW-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  、 乙腈 以 甲苯 为溶剂， 以96%的产率得到carbanide;chloroaluminum(2+);cyclopenta-1,3-diene;3,4-diphenylbut-3-en-2-ylideneazanide;zirconium(4+)
  参考文献：
  名称：

  含平面四配位碳的双金属化合物对不饱和有机底物的反应性

  摘要：

  Anti van't Hoff/le Bel compound 1 consisting of titanocene tolan and diethylborane units reacts with ethene, acetylenes, phosphaacetylenes, and acetone to give metallacycles 2, 3, 6, and 7, and in most cases the corresponding diethylorganylboranes are formed by hydroboration of the carbon-carbon or carbon-heteroatom multiple bond in the substrate. With nitriles the new bimetallic systems 9a-c (X-ray structure available for 9a) with titanium and boron centers and 12 containing zirconium and aluminium centers are generated by the formal insertion of the nitrile into the B-C-planar bond of 1 or the Al-C-planar bond of 11.

  DOI：

  10.1021/om00006a047