| 197391-92-7

• CAS: 197391-92-7
• 化学式: BF₄*C₁₉H₁₀MnO₃
• 分子量: 428.029
• InChiKey: MXLNPJOTUDZWDZ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 tetrabutylammonium borohydride 以 二氯甲烷 为溶剂， 以88%的产率得到
  参考文献：
  名称：

  Nucleophilic addition reactions of [(polyarene)Mn(CO)3]+ complexes containing naphthalene type ligands

  摘要：

  [(eta(6)-Polyarene)Mn(CO)(3)](+) complexes containing naphthalene type ligands undergo regioselective nucleophilic addition reactions with H- and C-donors to give moderate to good yields of eta(5)-cyclohexadienyl complexes. Products derived from hydride addition to naphthalene, phenanthrene and acenaphthene complexes have been characterized by X-ray diffraction.

  DOI：

  10.1016/s0020-1693(97)05506-0