4-amino-4'-ferrocenylstilbene | 161843-81-8

• 英文名称: 4-amino-4'-ferrocenylstilbene
• 英文别名: 4-amino-4'-ferocenylstilbene
• CAS: 161843-81-8
• 化学式: C₂₄H₂₁FeN
• 分子量: 379.284
• InChiKey: SADKVIZPTSUVKY-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  4-amino-4'-ferrocenylstilbene 、 在 triethylamine 作用下， 以 甲苯 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Second-Order Nonlinear Performance of Poly(methyl methacrylate) Films with Dispersed Donor−Acceptor Organobimetallic Compounds

  摘要：

  New organobimetallic Mo/Fe compounds of the type [Mo(Tp(An))(NO)(Cl)(Y-pi-bridge)(Fc)] {Tp(An) = hydrotris-(3-p-methoxyphenylpyrazol-1-yl)borate; Fc = (eta(5)-C5H4)Fe(eta(5)-C5H5); Y = NH (1), O (5), bridge = C6H4; Y NH, bridge C6H3R-N=N-C6H3R' [R = R' H (2); R = CH3, R' = H (3); R = R' = CH3 (4); Y = NH, bridge = C6H4-CH=CH-C6H4 (6)} have been synthesized and characterized. The second-harmonic generation yield of corona-poled spin-coated films of poly(methyl methacrylate) containing these compounds has been investigated. The three nonzero components, chi(31)((2)), chi(15)((2)), and chi(33)((2)), of the susceptibility tensor have been measured. chi 31(2) is the highest component at different with linear (one-dimensional) molecules where chi(33)((2)) = 3 chi(31)((2)) Moreover, Kleinman symmetry (chi(31)((2)) = chi(15)((2)) is not obeyed. These results have been discussed on the basis of a low-lying charge-transfer optical transition that has a perpendicular component to the permanent dipole moment. From the measured chi((2)) components, the molecular hyperpolarizabilities beta(33), beta(15), and beta(31) have been estimated under the assumption of thermal equilibrium under the poling field. On the ether hand, the role of diverse bridging structures on the susceptibilities, including different lengths (diarylazoamide vs anilide), as well as methyl substituents and linking (C-C vs N=N) groups, has been evaluated. Moreover, the acceptor [Mo(Tp(An))(NO)(Cl)(Y)] and nitro groups have been compared in compounds having the same ferrocenyl donor group and polarizable bridging system. chi(31)((2)) susceptibilities are significant in most cases, and values as high as 6.6 x 10(-9) esu have been obtained for the 4-nitro-4'-ferrocenylstilbene compound.

  DOI：

  10.1021/jp982764v

文献信息

• A new route to mixed oxo/arylimido complexes of molybdenum(VI) with a tris(pyrazolyl)borate co-ligand: syntheses, spectroscopic properties and ligand-centred redox activity
  作者：Siu-Ming Lee、Ralph Kowallick、Massimo Marcaccio、Jon A. McCleverty、Michael D. Ward

  DOI：10.1039/a804496a

  日期：——

  [Cl(O)(TpMe,Me)Mo}2 (NC6H4N)] 4. Reaction of various aminoferrocene derivatives Fc–X–NH2 with [Mo(TpMe,Me)(O)Cl2] afforded the dinuclear ferrocenyl–molybdenum complexes [Mo(O)(TpMe,Me)Cl(NXFc)] 5 (X = nothing), 6 (X = 1,4-C6H4), 7 (X = C6H4CHCHC6H4 with all para substitution) and 8 (X = C6H4NNC6H4 with all para substitution). Reaction of [Mo(TpMe,Me)(O)Cl2] with mixed amine–phenol ligands HO–X–NH2 afforded

  氧钼（V）前体[Mo（Tp Me，Me）（O）Cl 2 ] [Tp Me，Me  氢化三（3,5-二甲基吡唑-1-基）硼酸酯]与芳胺RNH 2的反应Et 3 N和空气的存在下，提供了氧代（亚氨基）钼（VI）配合物[Mo（O）（Tp Me，Me）Cl（NR）] 1（R = 4-甲苯基），2（R = C 6 H 4 NMe 2 -4）；这是获得这些稀有化合物的新途径。1,4-二氨基苯的使用，得到单核配合物3（R = C 6 H ^ 4 NH 2 -4）除了双核配合物[CL（O）（TPMe，Me）Mo} 2（NC 6 H 4 N）] 4.各种氨基二茂铁衍生物Fc–X–NH 2与[Mo（Tp Me，Me）（O）Cl 2 ]的反应得到双核二茂铁基–钼配合物[Mo（O）（Tp Me，Me）Cl（NXFc）] 5（X =无），6（X = 1,4-C 6 H 4），7（X = C 6 H 4 CHCHC