[(η(3)-C3H5)Pd(C9H9N3)]OSO2CF3 | 252955-02-5

• 英文名称: [(η(3)-C3H5)Pd(C9H9N3)]OSO2CF3
• CAS: 252955-02-5
• 化学式: CF₃O₃S*C₁₂H₁₄N₃Pd
• 分子量: 455.754
• InChiKey: YHQXBLSEBGQVHJ-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  bis(η3-allyl-μ-chloropalladium(II)) 、 2-(3-methylpyridin-2-yl)-imidazole 、 silver trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 生成 [(η(3)-C3H5)Pd(C9H9N3)]OSO2CF3
  参考文献：
  名称：

  Interconvertible Cationic and Neutral Pyridinylimidazole η³-Allylpalladium Complexes. Structural Assignment by ¹H, ¹³C, and ¹⁵N NMR and X-ray Diffraction

  摘要：

  Interconvertible cationic pyridinylimidazole eta(3)-allylpalladium complex 2 and neutral pyridinylimidazolyl eta(3)-allylpalladium complex 3 were synthesized and their structures analyzed by H-1, C-13, and N-15 NMR and X-ray diffraction. Cationic 2 and neutral 3 can be changed into each other by deprotonation and protonation.

  DOI：

  10.1021/om990647w