| 264609-10-1

• CAS: 264609-10-1
• 化学式: C₂₄BF₂₀*C₂₆H₃₀NZr
• 分子量: 1126.8
• InChiKey: CSDFYNXBVIRBLJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [H(OEt2)2][B(C6F5)4] 、 [C5H3(CH2CH2N(CH3)2)C(CH3)2(C13H8)]Zr(methyl)2 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, Crystal Structure, and Application of the Oxonium Acid [H(OEt₂)₂]⁺[B(C₆F₅)₄]^-

  摘要：

  The reaction of LiB(C6F5)(4) with HCl in diethyl ether afforded the new oxonium acid [H(OEt2)2](+)-[B(C6F5)(4)](-) (1) as a colorless crystalline solid, which was characterized by NMR spectroscopy, by elemental analysis, and by single-crystal X-ray diffraction. The application of 1 is demonstrated in the generation of the complex: {[eta(5)-C5H3(CH2CH2NMe2)CMe2-eta(5)-C13H8]ZrCH3}(+)- [B(C6F5)(4)](-) (3) containing an intramolecularly donor-stabilized alkylzirconocene cation.

  DOI：

  10.1021/om990612w