| 862999-51-7

• CAS: 862999-51-7
• 化学式: C₂₅H₄₅PRuSi
• 分子量: 505.762
• InChiKey: DCAIHQNTHMDRFI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Cp*Ru(iPr₃P)Cl] 、 苯硅烷 生成 、
  参考文献：
  名称：

  Cp*(iPr3P)Ru(Cl)(η2-HSiClMe2): the first complex with simultaneous Si–H and RuCl⋯SiCl inter-ligand interactions

  摘要：

  The addition of HSiMe2Cl to the unsaturated compound Cp*(iPr3P)RuCl gives an unstable adduct which, according to NMR (JH–Si = 33.5 Hz), X-ray crystal structure and DFT evidence, is a silane σ-complex Cp*(iPr3P)Ru(Cl)(η2-HSiMe2Cl) supported by an unprecedented, simultaneous inter-ligand RuCl⋯SiCl hypervalent interaction between the chloride ligand on ruthenium and the SiMe2Cl group.

  DOI：

  10.1039/b500679a