[(Fe(III)(N-(2-methoxyethyl)-N,N-bis(pyridin-2-yl-methyl)amine)(CF3SO3))2(μ-oxo)](2+) | 854275-75-5

• 英文名称: [(Fe(III)(N-(2-methoxyethyl)-N,N-bis(pyridin-2-yl-methyl)amine)(CF3SO3))2(μ-oxo)](2+)
• 英文别名: [[Fe(III)(mebpa)(CF3SO3)]2O](2+)
• CAS: 854275-75-5
• 化学式: C₃₂H₃₈F₆Fe₂N₆O₉S₂
• 分子量: 940.505
• InChiKey: RSAZIWIJDHMMMS-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [(Fe(III)(N-(2-methoxyethyl)-N,N-bis(pyridin-2-yl-methyl)amine)Cl)2(μ-oxo)](ClO4)2 、 silver trifluoromethanesulfonate 以 乙腈 为溶剂， 生成 [(Fe(III)(N-(2-methoxyethyl)-N,N-bis(pyridin-2-yl-methyl)amine)(CF3SO3))2(μ-oxo)](2+)
  参考文献：
  名称：

  Control of the catalytic oxidations mediated by an oxo-bridged non-heme diiron complex: role of additives and reaction conditions

  摘要：

  The catalytic activity of {[Fe(mebpa)Cl](2)O}(ClO4)(2) (1) (mebpa = N-(2-methoxyethyl)-NN-bis(pyridin-2-yl-methyl)amine) with H2O2 for the functionalization of alkanes and alkenes has been investigated. The experimental results show that compound I is stable during the catalytic cycle and it is an efficient catalyst for cyclohexane oxidation leading to an alcohol:ketone ratio of 3.5. Compound 1 is also found to be an active and selective catalyst for the epoxidation of alkenes. In all cases, the catalytic efficiency is strongly dependent on the presence of additives and the reaction conditions. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2004.09.002