| 242130-99-0

• CAS: 242130-99-0
• 化学式: C₃₂H₃₄Fe₂O
• 分子量: 546.315
• InChiKey: OAKFZVNLMHGXHE-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 N₂H₄*H₂O 、 Ac₂O 作用下， 以 乙醇 为溶剂， 以54%的产率得到E-isomer 2-acetyl-3-ferrocenyl-5-tert-butyl-7-ferrocenymethylidene-2,3,3a,4,5,6,7-heptahydroindazole
  参考文献：
  名称：

  Asymmetrical induction in the synthesis of ferrocenyl-substituted bicyclic pyrazolines.E,Z-Isomerization of the ferrocenylmethylidene fragment

  摘要：

  Asymmetrical induction in the synthesis of bicyclic ferrocenyl-substituted pyrazolines was studied. High diastereoselectivity of induction of the chiral center by the chiral center of the 1,2 type was observed. The cis diastereomer of 2-acetyt-3-ferrocenyl-7-ferrocenylmethylidene-2,3,3a,4,5,6,7-heptahydroindazole was studied by X-ray diffraction analysis. The E,Z-configurational isomerism of the ferrocenylmethylene fragment of pyrazolines in an acidic medium is described.

  DOI：

  10.1007/bf02496265