| 401947-42-0

• CAS: 401947-42-0
• 化学式: C₁₈H₁₉FeNO
• 分子量: 321.202
• InChiKey: BWNKUXMTZGGEGL-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 p-toluenesulfonic acid monohydrate 作用下， 以 甲苯 为溶剂， 以58%的产率得到(E)-1-[(R)-2-methylferrocenyl]-2-(4-pyridinyl)ethylene
  参考文献：
  名称：

  New chiral ferrocenyl-pyridinium salts for non-linear optics

  摘要：

  Three enantiomerically pure chiral analogues of 4-[(E)-2-ferrocenyl-ethenyl]pyridinium iodide have been synthesized. Their bulk efficiencies in second harmonic generation (SHG) have been measured (from 0 to 0.25 times that of urea). Furthermore, the crystal structures for two of them and for the parent 4-[(E)-2-ferrocenyl-ethenyl]pyridinium iodide have been determined by X-ray diffraction studies. Crystal packing could explain the very different SHG bulk efficiencies in this family of materials. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00974-3