[(2,6-bis(2,6-diisopropylanilidomethyl)pyridine)ThMe3(Li(dme))] | 1243337-85-0

• 英文名称: [(2,6-bis(2,6-diisopropylanilidomethyl)pyridine)ThMe3(Li(dme))]
• CAS: 1243337-85-0
• 化学式: C₃₈H₆₀LiN₃O₂Th
• 分子量: 841.788
• InChiKey: QXSMAUSDENZGLG-YLVISDFFSA-N

反应信息

• 作为反应物：
  描述：

  [(2,6-bis(2,6-diisopropylanilidomethyl)pyridine)ThMe3(Li(dme))] 以 氘代苯 为溶剂， 生成 [(2,6-NC5H3(CH2N(2,6-diisopropylphenyl))(CH2N(C6H3iPr(CMe2)-2,6)))Th(μ-(13)CD3)2Li(dme)]
  参考文献：
  名称：

  A thermally robust di-n-butyl thorium complex with an unstable dimethyl analogue

  摘要：

  Methyl and n-butyl thorium complexes of a rigid 2,6-bis(anilidomethyl)pyridine ligand have been prepared; the n-butyl complex is thermally stable, even at 60 °C, while the methyl complexes exhibit a high tendency to eliminate methane viaσ-bond metathesis.

  DOI：

  10.1039/c002122a
• 作为产物：
  描述：

  [(2,6-bis(2,6-diisopropylanilidomethyl)pyridine)ThCl2(dme)] 、 在 LiI 作用下， 生成 [(2,6-bis(2,6-diisopropylanilidomethyl)pyridine)ThMe3(Li(dme))]
  参考文献：
  名称：

  A thermally robust di-n-butyl thorium complex with an unstable dimethyl analogue

  摘要：

  Methyl and n-butyl thorium complexes of a rigid 2,6-bis(anilidomethyl)pyridine ligand have been prepared; the n-butyl complex is thermally stable, even at 60 °C, while the methyl complexes exhibit a high tendency to eliminate methane viaσ-bond metathesis.

  DOI：

  10.1039/c002122a