[6,6-(PEt3)2-closo-6,1-RhCB8H9] | 1240422-72-3

• 英文名称: [6,6-(PEt3)2-closo-6,1-RhCB8H9]
• CAS: 1240422-72-3
• 化学式: C₁₃H₃₉B₈P₂Rh
• 分子量: 446.794
• InChiKey: UIFKGXVRSRUYST-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [6,6-(PEt3)2-closo-6,1-RhCB8H9] 以 氘代氯仿 为溶剂， 生成 [6,7'-(μ-H)-6-PEt3-closo-6,1-RhCB8H8]2
  参考文献：
  名称：

  Two Metal−Monocarbollide Relatives of the {B₂₀H₁₈} Double-Cluster Boranes

  摘要：

  Reaction of nine-vertex [cluso-1-CB(8)H9](-) with sources of "{M(PEt3)(2)}(+)" (M = Rh or Pt) leads to double-cluster metallacarboranes of general formulation [M(PEt3)-CB8H9](2), whose gross molecular structures are different but nevertheless isomeric. The two {MCB8} clusters are interconnected by reciprocal B-H-M interactions and, in the case of Pt, by a Pt-Pt bond.

  DOI：

  10.1021/om100471n
• 作为产物：
  描述：

  chloro(1,5-cyclooctadiene)rhodium(I) dimer 、 [P(C₆H₅)4⁽¹⁺⁾][closo-1-CB₈H₉^(1-)] 、 三乙基膦 在 TlPF₆ 作用下， 以 二氯甲烷 为溶剂， 生成 [6,6-(PEt3)2-closo-6,1-RhCB8H9]
  参考文献：
  名称：

  Two Metal−Monocarbollide Relatives of the {B₂₀H₁₈} Double-Cluster Boranes

  摘要：

  Reaction of nine-vertex [cluso-1-CB(8)H9](-) with sources of "{M(PEt3)(2)}(+)" (M = Rh or Pt) leads to double-cluster metallacarboranes of general formulation [M(PEt3)-CB8H9](2), whose gross molecular structures are different but nevertheless isomeric. The two {MCB8} clusters are interconnected by reciprocal B-H-M interactions and, in the case of Pt, by a Pt-Pt bond.

  DOI：

  10.1021/om100471n