| 123857-69-2

• CAS: 123857-69-2
• 化学式: C₁₅H₃₃ClIrP₃
• 分子量: 534.021
• InChiKey: HRDPQYJXQIVMQV-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  thallium(I) hexafluorophosphate 、 以 水 为溶剂， 以75%的产率得到[(H)2(PMe3)3iridium(III)(μ-chloro)iridium(III)(H)(Ph)(PMe3)3]PF6
  参考文献：
  名称：

  Dinuclear iridium complexes with unsupported Ir–Cl–Ir bridges

  摘要：

  Two unusual dinuclear iridium complexes are reported with unsupported bridging chloride ligands. The first comes from an aqueous solution of H2ClIr(PMe3)(3) by the addition of KPF6.[GRAPHICS].The second is formed in the reaction between H(C6H5)ClIr(PMe3)(3) and TlPF6 in dichloromethane.[GRAPHICS].Single crystal X-ray structures are provided for both mu-chlorodiiridium complexes. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.04.014