(octacarbonyl)di(μ-tellurophenolato)-dimolybdenum(I) | 102516-06-3

• 英文名称: (octacarbonyl)di(μ-tellurophenolato)-dimolybdenum(I)
• 英文别名: Mo2(CO)8(μ-TePh)2
• CAS: 102516-06-3
• 化学式: C₂₀H₁₀Mo₂O₈Te₂
• 分子量: 825.375
• InChiKey: UFQZJCMRAJIWOF-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  (octacarbonyl)di(μ-tellurophenolato)-dimolybdenum(I) 以 neat (no solvent) 为溶剂， 生成 tellurium-molybdenum
  参考文献：
  名称：

  摘要：

  The thermal decay of 19 individual carbonyl homo- and heterochalcogenide clusters with different M/X ratios (M = Fe, Mn, Pt, Cr, W, Mo, Re, Ru; X = S, Se, Te) was studied by differential scanning calorimetry and thermogravimetry. The process is stepwise and occurs at relatively low temperatures (100-350 degreesC). The general fact of incomplete removal of carbon monoxide (due to the formation of carbide and oxide impurities) during thermolysis of carbonyl chalcogenide clusters with the M : X ratio greater than I was elucidated. Conversely, when M : X less than or equal to I (or at any M/X ratio for clusters containing methylcyclopentadienyl groups), pure metal chalcogenides are formed.

  DOI：

  10.1023/a:1022444231122
• 作为产物：
  描述：

  Mo2(CO)10(μ-diphenylditellurium) 以 not given 为溶剂， 生成 (octacarbonyl)di(μ-tellurophenolato)-dimolybdenum(I)
  参考文献：
  名称：

  Pasynskii; Torubaev; Drukovskii, Russian Journal of Inorganic Chemistry, 1997, vol. 42, # 6, p. 858 - 867

  摘要：

  DOI：

文献信息

• Vogt, Thomas; Straehle, Joachim, Zeitschrift für Naturforschung. Teil B, Anorganische Chemie, organische Chemie, <hi>1985</hi>, vol. 40, # 12, p. 1599 - 1602
  作者：Vogt, Thomas、Straehle, Joachim

  DOI：——

  日期：——