| 677297-06-2

• CAS: 677297-06-2
• 化学式: C₁₈H₂₂Ru
• 分子量: 339.443
• InChiKey: VSEKYMOTUOEKML-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 K₂CO₃ 、 CF₃SO₃H 作用下， 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Intramolecular Hydroalkylation as a Route to Strained Dicationic Bis(arene) [3]Ruthenocyclophanes

  摘要：

  Base-promoted intramolecular hydroalkylation of the carbon-carbon triple bond in the ruthenium bis(arene) complexes [(p-cymene)Ru(eta(6)-C(6)H(5)CdropCR)]-[OTf](2) (1, R = Et; 2, R = Ph; OTf = O3SCF3) generates the strained [3]ruthenocyclophane complexes 3 and 4, in which a propenyl (-CH2CR=CH-) group bridges the two arene ligands. The presence of the propenyl bridge results in a bent-metallocene structure for the [3]ruthenocyclophane cation in 4, with an angle of 11.8degrees between the arene ligands.

  DOI：

  10.1021/om010931z