[Ni(1,2-bis(4-mercapto-3,3-dimethyl-2-thiabutyl)benzene(2-))Ru(CO)2Cl2] | 890761-42-9

• 英文名称: [Ni(1,2-bis(4-mercapto-3,3-dimethyl-2-thiabutyl)benzene(2-))Ru(CO)2Cl2]
• CAS: 890761-42-9
• 化学式: C₁₈H₂₄Cl₂NiO₂RuS₄
• 分子量: 631.317
• InChiKey: AOUKJOAWVIUAJM-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  dicarbonyldichlororuthenium 、 [(bis(4-thiolato-3,3-dimethyl-2-thiabutyl)-o-phenylene)nickel(II)] 以 二氯甲烷 为溶剂， 生成 [Ni(1,2-bis(4-mercapto-3,3-dimethyl-2-thiabutyl)benzene(2-))Ru(CO)2Cl2]
  参考文献：
  名称：

  [Ni(xbsms)Ru(CO)₂Cl₂]: A Bioinspired Nickel−Ruthenium Functional Model of [NiFe] Hydrogenase

  摘要：

  As a model of the active site of [NiFe] hydrogenases, a dinuclear nickel - ruthenium complex [Ni(xbsms) Ru(CO)(2)Cl-2] was synthesized and fully characterized. The three-dimensional structure reveals a nickel center in a square-planar dithioether-dithiolate environment connected to a ruthenium moiety via a Ni(mu-SR)(2)Ru bridge. This complex catalyzes hydrogen evolution by electroreduction of the weakly acidic Et3NH+ ions in N,N-dimethylformamide and is therefore the first functional bioinspired model of [ NiFe] hydrogenases.

  DOI：

  10.1021/ic060510f