| 73117-46-1

• CAS: 73117-46-1
• 化学式: C₂₇H₂₅BCl₂N₆PRh
• 分子量: 649.132
• InChiKey: WOAIASHPEAYHMV-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  、 silver nitrate 以 甲醇 、 二氯甲烷 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Synthesis and Molecular Structure of [{(HBpz₃)Rh(PPh₃)(μ-Cl)₂}₂Ag]BF₄ (Hpz = Pyrazole), a Heterotrinuclear Rh₂Ag Compound with Square-Planar Silver(I)

  摘要：

  Reaction of [(HBpz(3))RhCl2(PPh3)] (Hpz = pyrazole) with silver salts AgA (A = BF4, NO3, SbF6) affords the unexpected heterotrinuclear compounds [{(HBpz(3))Rh(PPh3)(mu-Cl)(2)}(2)Ag]A (A = BF4 (1), NO3 (2), SbF6 (3)). The compounds have been fully characterized by IR, H-1, P-31{H-1}, and C-13{H-1} NMR spectroscopy and FAB(+) mass spectrometry. The solid structure of compound 1 was determined by single-crystal X-ray diffraction. The cation consists of two (HBpz(3))RhCl2(PPh3) units bonded to a silver atom through two double mu-Cl bridges in an unusual distorted square-planar arrangement.

  DOI：

  10.1021/ic011217c