tetra-μ-2-fluorobenzoato-κ10O:O';O:O,O';O:O';O,O':O'-bis[aqua(4,4'-bipyridine-κN)(2-fluorobenzoato-κO)lanthanum(III)] | 709030-87-5

• 英文名称: tetra-μ-2-fluorobenzoato-κ10O:O';O:O,O';O:O';O,O':O'-bis[aqua(4,4'-bipyridine-κN)(2-fluorobenzoato-κO)lanthanum(III)]
• 英文别名: tetra-μ-2-fluorobenzoato-bis[aqua(4,4'-bipyridine)(2-fluorobenzoato)lanthanum(III)]
• CAS: 709030-87-5
• 化学式: C₆₂H₄₄F₆La₂N₄O₁₄
• 分子量: 1460.85
• InChiKey: PVUDBUMZNPTRJQ-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  邻氟苯甲酸 、 4,4'-联吡啶 、 氯化镧水合物 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 生成 tetra-μ-2-fluorobenzoato-κ10O:O';O:O,O';O:O';O,O':O'-bis[aqua(4,4'-bipyridine-κN)(2-fluorobenzoato-κO)lanthanum(III)]
  参考文献：
  名称：

  Tetra-μ-2-fluorobenzoato-bis[aqua(4,4′-bipyridine)(2-fluorobenzoato)lanthanum(III)]

  摘要：

  Each La3+ ion in the title complex, tetra-mu-2-fluorobenzoato-kappa(10)O:O';O:O,O';O:O';O,O':O'-bis[aqua(4,4'-bipyridine-kappaN)(2-fluorobenzoato-kappaO)lanthanum(II)], [La(C7H4FO2)(6)(C10H8N2)(2)(H2O)(2)], is coordinated by six O atoms from the carboxylate groups of five 2-fluorobenzoate ligands, one O atom from a water molecule and one N atom from a 4,4'-bipyridine molecule, thus forming a dimeric molecule. An infinite one-dimensional dimeric supramolecular chain is formed via intermolecular hydrogen bonds.

  DOI：

  10.1107/s0108270103029470