Ru(η(5)-C5H5)(diphenylphosphine ferrocene)N3 | 745067-00-9

• 英文名称: Ru(η(5)-C5H5)(diphenylphosphine ferrocene)N3
• 英文别名: Ru(η-Cp)(1,1'-bis-diphenylphosphinoferrocene)N3；Ru(η(5)-C5H5)(dppf)N3
• CAS: 745067-00-9
• 化学式: C₃₉H₃₃FeN₃P₂Ru
• 分子量: 762.576
• InChiKey: CZIJDUHROVKATN-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  Ru(η(5)-C5H5)(diphenylphosphine ferrocene)N3 、 tin(II) bromide 以 乙醇 为溶剂， 生成 Ru(η(5)-C5H5)(diphenylphosphine ferrocene)SnBr3
  参考文献：
  名称：

  The synthesis and structural characterisation of [Ru(η-Cp)(dppf)SnBr3]

  摘要：

  The reaction of [Ru(eta-Cp)(dppf)N-3] (1) with equimolar amount of SnBr2 yielded an interesting heterotrimetallic compound [Ru(eta-Cp)(dppf)SnBr3] (2) (dppf: 1,1'-bis-diphenylphosphinoferrocene). Compounds I and 2 were characterised by IR, NMR (H-1, C-13, P-31 and Sn-119), and 2, additionally, by Fe-57 and Sn-119 Mossbauer spectroscopy and X-ray crystallography. The latter results were as follows: monoclinic, C2/c, a = 32.8879(4) Angstrom, b = 11.9888(2) Angstrom, c = 20.8986(3) Angstrom, beta = 92.545(1)degrees, V = 8231.9(2) Angstrom(3), Z = 8. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2003.12.012
• 作为产物：
  描述：

  sodium azide 、 chloro(η5-cyclopentadienyl)(1,1'-bis(diphenylphosphino)ferrocene)ruthenium(II) 以 乙醇 为溶剂， 以85%的产率得到Ru(η(5)-C5H5)(diphenylphosphine ferrocene)N3
  参考文献：
  名称：

  The synthesis and structural characterisation of [Ru(η-Cp)(dppf)SnBr3]

  摘要：

  The reaction of [Ru(eta-Cp)(dppf)N-3] (1) with equimolar amount of SnBr2 yielded an interesting heterotrimetallic compound [Ru(eta-Cp)(dppf)SnBr3] (2) (dppf: 1,1'-bis-diphenylphosphinoferrocene). Compounds I and 2 were characterised by IR, NMR (H-1, C-13, P-31 and Sn-119), and 2, additionally, by Fe-57 and Sn-119 Mossbauer spectroscopy and X-ray crystallography. The latter results were as follows: monoclinic, C2/c, a = 32.8879(4) Angstrom, b = 11.9888(2) Angstrom, c = 20.8986(3) Angstrom, beta = 92.545(1)degrees, V = 8231.9(2) Angstrom(3), Z = 8. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2003.12.012