potassium dioxoselenatovanadate(V) | 94491-66-4

• 英文名称: potassium dioxoselenatovanadate(V)
• CAS: 94491-66-4
• 化学式: K*O₂V*O₄Se
• 分子量: 264.996
• InChiKey: IBCQCTVBJPCJSE-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 potassium dioxoselenatovanadate(V)
  参考文献：
  名称：

  Synthesis, structure, and physicochemical properties of K[VO2(SeO4)(H2O)] and K[VO2(SeO4)(H2O)2] · H2O

  摘要：

  The vanadium(V) complexes K[VO2(SeO4)(H2O)] and K[VO2(SeO4)(H2O)(2)] center dot H2O were synthesized using original procedures; their physicochemical properties were studied, and the crystal structure was determined on the basis of X-ray diffraction and neutron diffraction data. The structure of K[VO2(SeO4)(H2O)(2)] center dot H2O is composed of VO6 octahedra connected to form infinite chains by bridging SeO4 tetrahedra. Each VO6 tetrahedron has short terminal V-O bonds forming the bent dioxovanadium group VO2+. The unit cell parameters of K[VO2(SeO4)(H2O)(2)] center dot H2O are a = 6.4045(1) angstrom, b = 9.9721(2) angstrom, c = 6.6104(1) angstrom, beta = 107.183(1)degrees, V = 403.34 angstrom(3), Z = 2, monoclinic system, space group P2(1). The complex K[VO2(SeO4)(H2O)] forms a two-dimensional layered structure composed of highly distorted VO6 octahedra having two short terminal V-O bonds and SeO4 groups coordinated simultaneously by three vanadium atoms. This compound crystallizes in the monoclinic system (space group P2(1)/c): a = 7.3783(1) angstrom, b = 10.5550(2) angstrom, c = 10.3460(2) angstrom, beta = 131.625(1)degrees, V = 602.894(5) angstrom(3), Z = 4. The vibrational spectra of the studied compounds are fully consistent with their structural features.

  DOI：

  10.1134/s0036023611080262