trans-platinum(II) diimine diacetylide chloride | 1333496-17-5

• 英文名称: trans-platinum(II) diimine diacetylide chloride
• CAS: 1333496-17-5
• 化学式: C₃₆H₆₂Cl₂N₂Pt
• 分子量: 788.888
• InChiKey: OJPJRTFRKLRAMT-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  、 trans-platinum(II) diimine diacetylide chloride 以 二氯甲烷 、 三乙胺 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and photophysical properties of two Platinum(II) diimine diacetylides – A new approach for fluorescent two-photon absorption materials from organometallics

  摘要：

  Two new arylalkyne ligands L1 (D-pi-D' type) and L2 (D-pi-A type), and their coordinated Platinum(II) diimine diacetylides 1 (D-pi-D'-pi-[Pt]-pi-D'-pi-D type) and 2 (D-pi-A-pi-[Pt]-pi-A-pi-D type) were designed and synthesized (where D represents electron donating group and A represents electron accepting group). Photophysical properties measurements indicated that 2 displayed orange-red fluorescence with relatively high fluorescence quantum yield and strong two-photon absorption (2PA) cross-section. The influence of metal on the electronic structure and property was investigated by theoretical calculations and cyclic voltammograms. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.cplett.2011.07.081