| 1310811-89-2

• CAS: 1310811-89-2
• 化学式: C₂₃H₃₈BrFeN₂OP₂*C₂₄H₂₀B
• 分子量: 875.5
• InChiKey: XOFGIHLDODLRGV-GKQCWGMMSA-M

反应信息

• 作为反应物：
  描述：

  在 KOC(CH₃)3 作用下， 以 苯 为溶剂， 生成 carbon monoxide;[(Z)-2-di(propan-2-yl)phosphanylethenyl]-[2-[(Z)-2-di(propan-2-yl)phosphanylethenyl]azanidylphenyl]azanide;iron(2+)
  参考文献：
  名称：

  Low-Valent Ene–Amido Iron Complexes for the Asymmetric Transfer Hydrogenation of Acetophenone without Base

  摘要：

  Examination of the role of base in the activation of our previously reported iron(II) complexes having the general formula [Fe(CO)(Br)(PNNP)][BPh(4)] revealed a five-coordinate iron(II) complex in which the tetradentate PNNP ligand had been doubly deprotonated. The new iron(II) complexes were used in the transfer hydrogenation of acetophenone in isoproparlol in the absence of added base, and certain analogues showed catalytic activity.

  DOI：

  10.1021/ja202375y