[(η⁵-C₅Me₅)Ru(2,6-dimethylphenyl isocyanide)₂(N₃)] | 1448666-19-0

• 英文名称: [(η⁵-C₅Me₅)Ru(2,6-dimethylphenyl isocyanide)₂(N₃)]
• CAS: 1448666-19-0
• 化学式: C₂₈H₃₃N₅Ru
• 分子量: 540.674
• InChiKey: YANDFYNMRIOZSH-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [(η⁵-C₅Me₅)Ru(2,6-dimethylphenyl isocyanide)₂(N₃)] 以 邻二甲苯 为溶剂， 反应 96.0h， 以63%的产率得到[(η⁵-C₅Me₅)Ru(2,6-dimethylphenyl isocyanide)₂(NCN-2,6-dimethylphenyl)]
  参考文献：
  名称：

  A Sandwich Zwitterionic Ruthenium Complex Bearing a Cyanamido Group

  摘要：

  A sandwich zwitterionic ruthenium complex (4) was prepared by an intramolecular 1,3-dipolar cydoaddition of the ruthenium azido isocyanide [CpMe5Ru(CNAr)(2)N-3] (2). The reaction involved a formal 1,3-migration mechanism along a highly conjugated system linking to a cyanamid group.

  DOI：

  10.1021/om400547r
• 作为产物：
  描述：

  sodium azide 、 [(η⁵-C₅Me₅)Ru(2,6-dimethylphenyl isocyanide)₂Cl] 以 乙醇 为溶剂， 反应 6.0h， 以90.1%的产率得到[(η⁵-C₅Me₅)Ru(2,6-dimethylphenyl isocyanide)₂(N₃)]
  参考文献：
  名称：

  A Sandwich Zwitterionic Ruthenium Complex Bearing a Cyanamido Group

  摘要：

  A sandwich zwitterionic ruthenium complex (4) was prepared by an intramolecular 1,3-dipolar cydoaddition of the ruthenium azido isocyanide [CpMe5Ru(CNAr)(2)N-3] (2). The reaction involved a formal 1,3-migration mechanism along a highly conjugated system linking to a cyanamid group.

  DOI：

  10.1021/om400547r