| 1150633-92-3

• CAS: 1150633-92-3
• 化学式: C₃₂H₂₈Cl₂Fe₂N₂O₂Pd₂
• 分子量: 868.027
• InChiKey: KFTIJZFUQIXPCE-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  吡啶 、 以 二氯甲烷 为溶剂， 反应 1.0h， 以68.5%的产率得到
  参考文献：
  名称：

  Synthesis, Characterization, and Crystal Structures of Heteroannular Cyclopalladated Ferrocenylimine-Pyridine Complexes

  摘要：

  Two new heteroannular cyclopalladated ferrocenylimine-pyridine derivatives, 2a and 2b, were easily prepared by the reaction of chlorine-bridged binuclear palladium complexes, 1a and 1b, with pyridine in high yields. They were characterized by ESI-MS, H-NMR, and IR spectra. The detailed structures of complexes 2a and 2b were determined by single-crystal X-ray analysis. According to the crystal structure, the palladium atom is bound to the unsubstituted Cp ring, forming a new heteroannular pyridine-cyclopalladated large-membered metallocycle. Complex 2a exists as a dimer in the crystal due to intermolecular CH(CHN)Cl hydrogen bonds, while 2b has a two-dimensional network structure formed by the intermolecular hydrogen bonds between the Cl atom with the adjacent C-H groups of Cp and pyridine.

  DOI：

  10.1080/15533174.2012.684267