trans-[Ru(N(4)-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh3)2Cl]Cl | 1020544-91-5

• 英文名称: trans-[Ru(N(4)-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh3)2Cl]Cl
• CAS: 1020544-91-5
• 化学式: C₅₁H₄₆ClN₄P₂RuS*Cl
• 分子量: 980.943
• InChiKey: BQWKILLTULBZMH-CNSXDPAZSA-L

反应信息

• 作为产物：
  描述：

  cis-[Ru(N(4)-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh3)2Cl]Cl 以 二氯甲烷-D2 为溶剂， 生成 trans-[Ru(N(4)-meta-tolyl-2-acetylpyridine thiosemicarbazone)(PPh3)2Cl]Cl
  参考文献：
  名称：

  Ruthenium(II) complexes containing N(4)-tolyl-2-acetylpyridine thiosemicarbazones and phosphine ligands: NMR and electrochemical studies of cis–trans isomerization

  摘要：

  [Ru(HL)(PPh3)(2)Cl]Cl complexes have been obtained in which HL = N(4)-ortho (complex 1), N(4)-meta (complex 2) and N(4) pctratolyl 2-acetylpyridine thiosemicarbazone (complex 3). NMR and electrochemical studies indicate that both cis and trans isomers exist in solution, and that the cis isomers are converted into the trans isomers with time. Crystal structure determination of (1) reveals that the traps isomer is formed in the solid state. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2007.04.032