| 942984-38-5

• CAS: 942984-38-5
• 化学式: C₁₈H₁₃Cl₃N₂OPd
• 分子量: 486.093
• InChiKey: BLBOWCBCEUBUFJ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  bis(η3-allyl-μ-chloropalladium(II)) 、 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, spectroscopic and structural characterization of the reaction products of quaternary cationic 2,2′-bipyridylium ligand bromide salts with metal halides

  摘要：

  The synthesis and spectroscopic characterization of quaternary salts containing 2,2,-bipyridine, 1,10-phenanthroline, 4,7-dimethyl1,10-phenanthroline and 3,4,7,8-tetramethyl-1,10-phenanthroline is reported. The coordinating behaviour of the bipyridylium salts toward palladium, copper and dimethyltin(IV)halides is investigated. The reaction of N-R,2,2-bipyridylium (= L-1) bromide (R = 4-Cl-C6H4 center dot CO center dot CH2) with palladium(11) chloride in acetonitrile solution yields a crystalline product, shown by a single crystal X-ray study to be L1PdX(3), where X is a Cl/Br (1:1) composite. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.12.037