| 376368-47-7

• CAS: 376368-47-7
• 化学式: C₁₂₁
• 分子量: 1453.33
• InChiKey: JQNFQQMWXWUEMC-ZVIYGNQRSA-N

物化性质

• 密度：
  3.97±0.1 g/cm3(Predicted)

反应信息

• 作为产物：
  描述：

  足球烯 以 neat (no solvent) 为溶剂， 生成 、
  参考文献：
  名称：

  Photochemical and Photophysical Properties of Three Carbon-Bridged Fullerene Dimers:  C₁₂₁ (I, II, III)

  摘要：

  The photochemical and photophysical properties of the three C-121 isomers (I, II, III) were investigated with MADLI-TOF-MS, UV-vis spectra, fluorescence spectra, absorption spectra of their DMA complexes, and theoretical calculations. The three isomers of C-121 (I, II, III) have different stabilities under laser irradiation, but isomer I and isomer II show good stability against the heat-induced conversion between different isomers: No conversion between the isomers was found after heating the mixture of isomer I and isomer II at 353 K for 12 h in Ar atmosphere. The results of UV-vis absorption and fluorescence spectra indicate that interactions between two C-60 moieties of C60CC60 in the ground and singlet states are not significant, C-121 (I, II, III) behaves as an electron-acceptor similar to C-60. These indicate that the formation of the fullerene chain structure (e.g., C60CC60) does not disturb the photochemical and photophysical properties of the C-60 monomer itself, even that the properties were enhanced by the formation of the polymer. This is significant for the C-60 polymer in photochemical or photoelectronic applications in which C60CC60 can be an excellent basic unit of polymers.

  DOI：

  10.1021/jp0701688