| 207388-19-0

• CAS: 207388-19-0
• 化学式: C₄₆H₅₄Cl₄N₂P₄Pd₂
• 分子量: 1113.5
• InChiKey: CCJAYGSTNKHAAL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四(三苯基膦)钯 、 Chlormethyl-dimethylaminochlorophosphin 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Selective C–Cl versus P–Cl activation—syntheses of complexes with P–Cl functional phosphinomethyl bridges η2,μ2-{P(R)Cl–CH2}

  摘要：

  On reaction of chloromethylchlorophosphines Cl(R)P-CH2-Cl with Pd(Ph3P)(4) the C-Cl bond is selectively activated by oxidative addition to Pd(0), unusual dipalladium complexes with P-Cl functional eta(2),mu(2){CH2-P(R)Cl} bridges being formed with high diastereoselectivity. The X-ray structure of 3a (R = tBu) reveals a chair-shaped Pd2P2C2 six-membered ring system with the substituents (Cl, tBu) at the two m(2)-P atoms in cis-position. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00717-1