| 192319-08-7

• CAS: 192319-08-7
• 化学式: C₄₄H₃₅N₃PRu*F₆P
• 分子量: 882.79
• InChiKey: LPWZZMHXRCHTSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 二(三苯基膦)环戊二烯基氯化钌(II) 、 4'-苯基-2,2':6',2''-三联吡啶 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and molecular structure of [CpRu(PPh3)(Phterpy-N,N′)]Cl complex: Hdentate nature of phterpy and diterpy

  摘要：

  Ligand displacement reactions of the complex [CpRu(PPh3)(2)Cl] were investigated with N, terdentate ligands, 4'-phenyl-2,2': 6,2 ''-terpyridine (Phterpy) and 1,4-bis(2,2': 6',2 ''-terpyridin-4-yl)benzene (diterpy). The [CpRu(PPh3)(2)Cl] reacted with these ligands to form stable complexes of the type [CpRu(PPh3)(Phterpy)]X (X = Cl-, PF6-) and [{CpRu(PPh3)}(diterpy){Ru(PPh3)Cp}]X-2 (X = Cl-, PF6-) where the respective ligands coordinate in a bidentate fashion. The X-ray crystal structure of the former complex was determined showing octahedral geometry about the metal center assuming the cyclopentadienyl ligand occupying three coordination sites and Phterpy acts as a bidentate ligand. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00585-2