[Ru(Ph-tpy)(5,5’-dvbpy)(Cl)][PF₆] | 1431662-79-1

• 英文名称: [Ru(Ph-tpy)(5,5’-dvbpy)(Cl)][PF₆]
• 英文别名: [Ru(4'-phenyl-2,2':6',2''-terpyridine)(5,5'-divinyl-2,2'-bipyridine)(Cl)][PF₆]
• CAS: 1431662-79-1
• 化学式: C₃₅H₂₇ClN₅Ru*F₆P
• 分子量: 799.12
• InChiKey: FGNCTUHWUDBXPY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 [Ru(Ph-tpy)(5,5’-dvbpy)(Cl)][PF₆] 、 乙腈 在 silver tetrafluoroborate 作用下， 以 水 为溶剂， 以74%的产率得到[Ru(Ph-tpy)(5,5’-dvbpy)(MeCN)][PF₆]
  参考文献：
  名称：

  Coordination Chemistry of Single-Site Catalyst Precursors in Reductively Electropolymerized Vinylbipyridine Films

  摘要：

  Reductive electropolymerization of [Ru-II(PhTpy)(5,5'-dvbpy)(Cl)](PF6) and [Ru-II(PhTpy)(5,5'-dvbPY)(MeCN)](PF6)(2) (PhTpy is 4'-phenyl-2,2':6',2 ''-terpyridine; 5,5'-dvbpy is 5,5'-divinyl-2,2'-bipyridine) on glassy carbon electrodes gives well films of poly{[Ru-II(PhTpy)(5,5'-dvbpy)(Cl)] (PF6)} (poly-1) or poly{[Ru-II(PhTpy)(5,5'-dvbpy)(MeCN)](PF6)(2)} (poly 2) Oxidative cycling of poly-2 with added NO3- results in the replacement of coordinated MeCN by NO3-, to give poly{[Ru-II(PhTpy) (5,5'-dvbpy) (NO3)](+)}, and with 0.1 M HClO4, replacement by H2O occurs to give poly{[Ru-II(PhTpy)(5,5'-dvbpy)(OH2)](2+)} (poly-OH2). Although analogous aqua complexes (e g, [Ru(tpy)(bpy)(OH2)](2+)) undergo rapid loss of H2O to MecN solution, poly-OH2 and poly-OH2+ are substitutionally inert in MeCN. The substitution chemistry is reversible, with reductive scans of poly-1 or poly-OH2 in MeCN resulting in poly-2, although with some loss of Faradaic response.

  DOI：

  10.1021/ic302472r
• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 [(4'-phenyl-2,2':6',2''-terpyridine)Ru(Cl)(μ-Cl)]₂ 、 4'-苯基-2,2':6',2''-三联吡啶 以 乙醇 、 水 为溶剂， 反应 0.25h， 以76%的产率得到[Ru(Ph-tpy)(5,5’-dvbpy)(Cl)][PF₆]
  参考文献：
  名称：

  Coordination Chemistry of Single-Site Catalyst Precursors in Reductively Electropolymerized Vinylbipyridine Films

  摘要：

  Reductive electropolymerization of [Ru-II(PhTpy)(5,5'-dvbpy)(Cl)](PF6) and [Ru-II(PhTpy)(5,5'-dvbPY)(MeCN)](PF6)(2) (PhTpy is 4'-phenyl-2,2':6',2 ''-terpyridine; 5,5'-dvbpy is 5,5'-divinyl-2,2'-bipyridine) on glassy carbon electrodes gives well films of poly{[Ru-II(PhTpy)(5,5'-dvbpy)(Cl)] (PF6)} (poly-1) or poly{[Ru-II(PhTpy)(5,5'-dvbpy)(MeCN)](PF6)(2)} (poly 2) Oxidative cycling of poly-2 with added NO3- results in the replacement of coordinated MeCN by NO3-, to give poly{[Ru-II(PhTpy) (5,5'-dvbpy) (NO3)](+)}, and with 0.1 M HClO4, replacement by H2O occurs to give poly{[Ru-II(PhTpy)(5,5'-dvbpy)(OH2)](2+)} (poly-OH2). Although analogous aqua complexes (e g, [Ru(tpy)(bpy)(OH2)](2+)) undergo rapid loss of H2O to MecN solution, poly-OH2 and poly-OH2+ are substitutionally inert in MeCN. The substitution chemistry is reversible, with reductive scans of poly-1 or poly-OH2 in MeCN resulting in poly-2, although with some loss of Faradaic response.

  DOI：

  10.1021/ic302472r