cis-Pt(triphenyl phosphite)2(Cl)(C2Cl) | 195395-25-6

• 英文名称: cis-Pt(triphenyl phosphite)2(Cl)(C2Cl)
• CAS: 195395-25-6
• 化学式: C₃₈H₃₀Cl₂O₆P₂Pt
• 分子量: 910.586
• InChiKey: FWSWXCGBUFXTDI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  亚磷酸三苯酯 、 trans-Pt(PPh3)2(Cl)(C2Cl) 以 二氯甲烷 为溶剂， 生成 cis-Pt(triphenyl phosphite)2(Cl)(C2Cl)
  参考文献：
  名称：

  Coordination chemistry of perhalogenated cyclyopentadienes and alkynes—XXI. Studies on the substitution reactions of Pt(PPh3)2(C2Cl2) and trans-Pt(PPh3)2(Cl)(C2Cl) with triphenylphosphite

  摘要：

  The reactions of the Pt(0) pi-alkyne complex Pt(PPh3)(2)(CI C equivalent to CCl) and the Pt-II alkynyl complex Pt(PPh3)(2)(Cl)(C equivalent to CCl) with P(OPh)(3) lead to either the pi-alkyne complexes Pt(PPh3)(n)(P(OPh)(3))(2-n)(Cl C equivalent to CCl) (n = 0, 1) or the cis and trans isomers of Pt(PPh3)(n)[P(OPh)(3)](2-n) (Cl)(C equivalent to CCl) (n = 0, 1), depending on the reaction conditions. The course of the reaction was followed by P-31-NMR spectroscopy, from which a plausible mechanism for the oxidative addition reaction can be derived: key steps are phosphine dissociation from the Pt(0) species to a two-coordinate intermediate, which undergoes oxidative addition of a C-Cl bond to give a three-coordinate Pt-II species, which might be stabilized by dimerization. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00087-9