| 343781-89-5

• CAS: 343781-89-5
• 化学式: C₁₇H₁₉IN₂O₂Pt
• 分子量: 605.335
• InChiKey: HTDWIQQHMIFZDJ-ZMKTYRQVSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 KI 作用下， 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Stabilization of unstable unsaturated molecules in five-coordinate TBP complexes of Pt(II): enol, diol and dialdehyde derivatives

  摘要：

  Protection and stabilization of some unstable olefins has been effectively achieved by coordination in live-coordinate [PtClMe(2,9-Me-2-1,10-phenanthroline)(olefin)] complexes. These have been characterized by H-1-NMR spectroscopy and iu the case of [PtClMe(2,9-Me-2-1,10-phenanthroline)(Z-EtCH=CHOH)] by X-ray diffractometry. Chemoselective reactions have been accomplished on the complexes, some of them involving alcoholic or aldehydic functions of the unsaturated ligand. (C) 2001 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00645-3