| 1246368-69-3

• CAS: 1246368-69-3
• 化学式: C₂₀H₃₆Si₂Zr
• 分子量: 423.901
• InChiKey: QJFATLOKMVUFLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三(五氟苯基)硼烷 以 benzene-d6 为溶剂， 生成
  参考文献：
  名称：

  Asymmetric activation of dialkyl zirconocenes

  摘要：

  Asymmetric alkylmethyl zirconocene derivatives were readily synthesised from Cp(2)ZrCl(CH(3)), and the appropriate alkyllithium reagent. The alkyl groups contain a silyl functionality on the beta-position. These asymmetric dialkyl zirconocenes were successfully activated by B(C(6)F(5))(3), selectively abstracting the methyl group. The clear difference in the (13)C NMR resonances, due to the alkyl groups on the cationic zirconocene made it possible to conclude that selective activation of this class of compounds was possible. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.06.011
• 作为产物：
  描述：

  zirconocene methyl chloride 、 以 diethyl ether 为溶剂， 生成
  参考文献：
  名称：

  Asymmetric activation of dialkyl zirconocenes

  摘要：

  Asymmetric alkylmethyl zirconocene derivatives were readily synthesised from Cp(2)ZrCl(CH(3)), and the appropriate alkyllithium reagent. The alkyl groups contain a silyl functionality on the beta-position. These asymmetric dialkyl zirconocenes were successfully activated by B(C(6)F(5))(3), selectively abstracting the methyl group. The clear difference in the (13)C NMR resonances, due to the alkyl groups on the cationic zirconocene made it possible to conclude that selective activation of this class of compounds was possible. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.06.011