| 162616-24-2

• CAS: 162616-24-2
• 化学式: BF₄*C₄₃H₃₈O₅P₂Rh
• 分子量: 886.429
• InChiKey: VYYAVWSAJVOSIH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Singewald, Elizabeth T.; Mirkin, Chad A.; Levy, Allison D., Angewandte Chemie, 1994, vol. 106, # 23/24, p. 2524 - 2526

  摘要：

  DOI：
• 作为产物：
  描述：

  在 CO 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Singewald, Elizabeth T.; Mirkin, Chad A.; Levy, Allison D., Angewandte Chemie, 1994, vol. 106, # 23/24, p. 2524 - 2526

  摘要：

  DOI：

文献信息

• Novel Hemilabile (Phosphinoalkyl)arene Ligands:  Mechanistic Investigation of an Unusual Intramolecular, Arene−Arene Exchange Reaction
  作者：Elizabeth T. Singewald、Xiaobo Shi、Chad A. Mirkin、Susan J. Schofer、Charlotte L. Stern

  DOI：10.1021/om960114c

  日期：1996.6.25

  The novel, hemilabile (phosphinoalkyl)arene ligands ArX(CH2)(2)PPh(2) (1a, Ar = C6H5, X = O; 1b, Ar = C6H5, X = CH2; 1c, Ar = FC6H4, X = CH2) were synthesized and complexed to Rh(I) to form the bis(phosphine), eta(6)-arene piano stool complexes [(eta(6):eta(1)-ArX(CH2)(2)PPh(2))Rh(eta(1)-ArX(CH2)(2)PPh(2))]BF4 (2a-c). Complexes 2a-c were fully characterized in solution, and complex 2a was characterized by single-crystal X-ray diffraction methods. Two of these complexes, 2a,c, undergo an unusual, degenerate eta(6)-arene, free arene exchange reaction which was studied by 2-D NMR EXSY experiments. A mechanism for the exchange reaction of 2a which involves the formation of a square planar, cis-phosphine, cis-ether Rh(I) complex, [Rh(eta(2)-PhO(CH2)(2)PPh(2))(2)]BF4 (13), is proposed.