1,1'-bis(undecenylseleno)ferrocene | 175440-73-0

• 英文名称: 1,1'-bis(undecenylseleno)ferrocene
• CAS: 175440-73-0
• 化学式: C₃₂H₅₀FeSe₂
• 分子量: 648.516
• InChiKey: GWVIXGSORZKGQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  三乙氧基硅烷 、 1,1'-bis(undecenylseleno)ferrocene 在 四(三苯基膦)铂 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of polysiloxane-supported ferrocenyl selenoether platinum complexes and their catalytic behavior in the hydrosilylation of olefins with triethoxysilane

  摘要：

  Polysiloxane-supported ferrocenyl selenoether platinum complex was prepared from 1,1'-bis(undecenylseleno)ferrocene via hydrosilylation with triethoxysilane, followed by immobilization on fumed silica and then reaction with potassium chloro-platinite. Fumed silica-bound (undecenylseleno)- or 1,1'-bis(undecenylseleno)ferrocene platinum complexes were also synthesized from triethoxysilane and (undecenylseleno)- or 1,1'-bis(undecenylseleno)ferrocene platinum complex directly. The platinum complexes of ferrocenyl selenoether and polymer-supported ferrocenyl selenoether were efficient catalysts for hydrosilylation of olefins with triethoxysilane. The catalytic activity of polysiloxane-supported platinum complexes (prepared by the method of immobilization after coordination) was similar to those of the corresponding ferrocenyl selenoether platinum complexes and higher than those of catalysts prepared by the method of coordination after immobilization.

  DOI：

  10.1016/s0022-328x(96)06873-8
• 作为产物：
  描述：

  二茂铁 、 1,2-di(undec-10-en-1-yl)diselane 在 正丁基锂 、 四甲基乙二胺 作用下， 以 正己烷 、 苯 为溶剂， 生成 (undecenylseleno)ferrocene 、 1,1'-bis(undecenylseleno)ferrocene
  参考文献：
  名称：

  Synthesis of polysiloxane-supported ferrocenyl selenoether platinum complexes and their catalytic behavior in the hydrosilylation of olefins with triethoxysilane

  摘要：

  Polysiloxane-supported ferrocenyl selenoether platinum complex was prepared from 1,1'-bis(undecenylseleno)ferrocene via hydrosilylation with triethoxysilane, followed by immobilization on fumed silica and then reaction with potassium chloro-platinite. Fumed silica-bound (undecenylseleno)- or 1,1'-bis(undecenylseleno)ferrocene platinum complexes were also synthesized from triethoxysilane and (undecenylseleno)- or 1,1'-bis(undecenylseleno)ferrocene platinum complex directly. The platinum complexes of ferrocenyl selenoether and polymer-supported ferrocenyl selenoether were efficient catalysts for hydrosilylation of olefins with triethoxysilane. The catalytic activity of polysiloxane-supported platinum complexes (prepared by the method of immobilization after coordination) was similar to those of the corresponding ferrocenyl selenoether platinum complexes and higher than those of catalysts prepared by the method of coordination after immobilization.

  DOI：

  10.1016/s0022-328x(96)06873-8