[Pd(2,6-(Ph2PCH2)2C6H3)(pyridine)](BF4) | 851576-78-8

• 英文名称: [Pd(2,6-(Ph2PCH2)2C6H3)(pyridine)](BF4)
• CAS: 851576-78-8
• 化学式: BF₄*C₃₇H₃₂NP₂Pd
• 分子量: 745.84
• InChiKey: XUMAFBCTXZCYET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pd(2,6-(Ph2PCH2)2C6H3)(pyridine)](BF4) 、 [Pd(2,6-((pentafluorophenyl)2PCH2)2C6H3)(acetonitrile)](BF4) 以 二氯甲烷-D2 为溶剂， 生成 [Pd(2,6-(Ph2PCH2)2C6H3)(acetonitrile)](BF4) 、 [Pd(2,6-((pentafluorophenyl)2PCH2)2C6H3)(pyridine)](BF4)
  参考文献：
  名称：

  Electron-Poor Pentafluorophenyl-Substituted PCP−Palladium Pincer Complexes

  摘要：

  A novel fluoroaryl-substituted PCP ligand has been synthesized and used to generate the corresponding Pd complexes. The bonding of the fluoroaryl phosphine has been investigated by X-ray crystallography, NMR spectroscopy, and a competition experiment, which indicate that the ligand is sterically comparable to its well-known phenyl analogue but clearly imparts significant electronic differences to the metal center.

  DOI：

  10.1021/om0500063
• 作为产物：
  描述：

  吡啶 、 [Pd(2,6-(Ph2PCH2)2C6H3)(acetonitrile)](BF4) 以 二氯甲烷 为溶剂， 生成 [Pd(2,6-(Ph2PCH2)2C6H3)(pyridine)](BF4)
  参考文献：
  名称：

  Electron-Poor Pentafluorophenyl-Substituted PCP−Palladium Pincer Complexes

  摘要：

  A novel fluoroaryl-substituted PCP ligand has been synthesized and used to generate the corresponding Pd complexes. The bonding of the fluoroaryl phosphine has been investigated by X-ray crystallography, NMR spectroscopy, and a competition experiment, which indicate that the ligand is sterically comparable to its well-known phenyl analogue but clearly imparts significant electronic differences to the metal center.

  DOI：

  10.1021/om0500063