| 1196083-68-7

• CAS: 1196083-68-7
• 化学式: C₃₉H₇₂Cl₂O₂P₆Ru₂S₂
• 分子量: 1096.02
• InChiKey: XUMJVFBPIDWLHK-UHFLAWAGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 二氯甲烷 为溶剂， 生成 [RuCl(CO)(PMe3)3]2(μ-CH=CH-1,2-bis(2-methylthiophen-3-yl)cyclopentene-CH=CH)
  参考文献：
  名称：

  Syntheses and Properties of Binuclear Ruthenium Vinyl Complexes with Dithienylethene Units as Multifunction Switches

  摘要：

  A series of binuclear ruthenium vinyl complexes with dithienylethene units, [RuCl(CO)(PMe3)(3)](2)-(mu-CH=CH-DTE-CH=CH) (5a, 5b), [RuCl(CO)(Py)(PPh3)(2)](2) (mu-CH=CH-DTE-CH=CH) (6a, 6b), [RuTp(CO)(PPh3)](2) (mu-CH=CH-DTE-CH=CH) (7a, 7b), and [RuCl(CO)(PMP)](2)(mu-CH=CH-DTE-CH=CH) (8a, 8b) (DTE = 1,2-bis(2-methylthiophen-3-yl)cyclopentene; 1,2-bis(2-methylthiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopentene), have been prepared. The respective products have been characterized by elemental analyses, NMR spectrometry, and UV/vis spectrophotometry. The structures of 3a and 5b have been established by X-ray crystallography. It is revealed that the binuclear ruthenium vinyl complexes with dithienylethene units show photochromic behavior, but their absorption spectra, cyclization/cycloreversion quantum yields, and the efficiency of the photochromic process are highly dependent on the central switching units and the ancillary ligands attached to the metal. Electrochemical studies have shown that the open-ring isomers of the metal complexes are triggered, either by light or electricity, to convert to their closed forms. It has clearly been demonstrated that these complexes represent it class of light- and electrotriggered multifunctional switch molecules featuring electrochromism, elcctrocyclization, and photo/electrotuning of the electronic communication.

  DOI：

  10.1021/om900396b
• 作为产物：
  描述：

  [RuCl(CO)(PMe3)3]2(μ-CH=CH-1,2-bis(2-methylthiophen-3-yl)cyclopentene-CH=CH) 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Syntheses and Properties of Binuclear Ruthenium Vinyl Complexes with Dithienylethene Units as Multifunction Switches

  摘要：

  A series of binuclear ruthenium vinyl complexes with dithienylethene units, [RuCl(CO)(PMe3)(3)](2)-(mu-CH=CH-DTE-CH=CH) (5a, 5b), [RuCl(CO)(Py)(PPh3)(2)](2) (mu-CH=CH-DTE-CH=CH) (6a, 6b), [RuTp(CO)(PPh3)](2) (mu-CH=CH-DTE-CH=CH) (7a, 7b), and [RuCl(CO)(PMP)](2)(mu-CH=CH-DTE-CH=CH) (8a, 8b) (DTE = 1,2-bis(2-methylthiophen-3-yl)cyclopentene; 1,2-bis(2-methylthiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopentene), have been prepared. The respective products have been characterized by elemental analyses, NMR spectrometry, and UV/vis spectrophotometry. The structures of 3a and 5b have been established by X-ray crystallography. It is revealed that the binuclear ruthenium vinyl complexes with dithienylethene units show photochromic behavior, but their absorption spectra, cyclization/cycloreversion quantum yields, and the efficiency of the photochromic process are highly dependent on the central switching units and the ancillary ligands attached to the metal. Electrochemical studies have shown that the open-ring isomers of the metal complexes are triggered, either by light or electricity, to convert to their closed forms. It has clearly been demonstrated that these complexes represent it class of light- and electrotriggered multifunctional switch molecules featuring electrochromism, elcctrocyclization, and photo/electrotuning of the electronic communication.

  DOI：

  10.1021/om900396b