[Pd2Cl4(Py)2] | 92937-81-0

• 英文名称: [Pd2Cl4(Py)2]
• 英文别名: (pyridine)2Pd2Cl4；[Pd2Cl4(pyridine)2]
• CAS: 92937-81-0
• 化学式: C₁₀H₁₀Cl₄N₂Pd₂
• 分子量: 512.855
• InChiKey: HJPJPYJXYLXDPK-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶 、 di-μ-chloro-dichloro[1,3-bis(3,5-di-tert-butylpyrazolyl-1-carbonyl)benzene]dipalladium(II) 以 not given 为溶剂， 生成 [Pd2Cl4(Py)2]
  参考文献：
  名称：

  Benzenedicarbonyl and benzenetricarbonyl linker pyrazolyl complexes of palladium(ii): synthesis, X-ray structures and evaluation as ethylene polymerisation catalystsElectronic supplementary information (ESI) available: molecular structures and bond lengths and angles for L2, L3, L6 and 2. See http://www.rsc.org/suppdata/dt/b2/b208376k/

  摘要：

  A series of novel compounds with pyrazolyl rings (pz) linked by benzenedicarbonyl (L1-L4) and benzenetricarbonyl (L5, L6) have been prepared and structurally characterized. The mutual orientation of their rings was studied by molecular mechanics. These polydentate species react with PdCl2(NCMe)(2) to yield dinuclear complexes in which the Pd centers coordinate to one or two pz units, a terminal chloride and two bridging chloride ligands. In complex [{(3,5-tBu(2)pzCO)(3)-1,3,5-C6H4}Pd2Cl2(mu-Cl)(2)](4) the pyrazolyl ligand L5 acts as a bidentate donor despite the presence of the third pz group. These Pd complexes, when activated with methylaluminoxide (MAO), exhibit activity in ethylene polymerization.

  DOI：

  10.1039/b208376k

文献信息

• Roof-Shaped Halide-Bridged Bimetallic Complexes via Ring Expansion Reaction
  作者：Clarite Azerraf、Shmuel Cohen、Dmitri Gelman

  DOI：10.1021/ic060700q

  日期：2006.8.1

  structures. New palladium and rhodium complexes featuring strongly bent (ca. 115 degrees ) M2(mu-Cl2) cores with very closely spanned metal centers (less than 3 A) have been prepared using the described ring-expansion reaction and have been fully characterized. Despite a constrained arrangement of the binuclear system, halogen bridges in all new compounds were stable in both the solid state and solution

  刚性三萜基配体的双核行为已得到研究。已证明带有1,8-双（二​​异丙基膦基）三茂铁（L1）和1-二异丙基膦基-8-二苯基膦基三茂铁（L2）的跨跨过渡金属单核配合物通过扩环与适当的过渡金属前体反应形成异常的双金属准封闭结构的途径。使用所述的扩环反应已经制备出了新的钯和铑配合物，这些配合物具有强烈弯曲（约115度）的M2（mu-CL2）核，具有非常紧密分布的金属中心（小于3 A），并且已得到充分表征。尽管双核系统的布置受到限制，所有新化合物中的卤素桥在固态和溶液中都是稳定的，即使存在添加的Lewis碱也没有解离的趋势。还讨论了将不对称的Pd2（mu-Cl）2CL2（1-二异丙基膦基-8-二苯基膦基三萜烯）（2）自发拆分为对映体纯对映体。