| 1173823-88-5

• CAS: 1173823-88-5
• 化学式: C₂₁H₄₀N₂Si₃Yb
• 分子量: 577.858
• InChiKey: XKKKLRMVUGVXPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 氧气 以 甲苯 为溶剂， 以43%的产率得到bis(trimethylsilyl)azanide;dimethyl-oxido-(2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)silane;1-[dimethyl-(2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)silyl]pyrrol-2-olate;pyrrol-1-ide;ytterbium(3+)
  参考文献：
  名称：

  C−H and Si−N Bond Oxygenations of a Divalent Ytterbium Amide of the Pyrrolyl-Cyclopentadienyl Ligand

  摘要：

  Reaction of Me4C5H-SiMe2-NC4H4 with Yb[N-(SiMe3)(2)](2)(THF)(2) yielded a new type of ansa-sandwich divalent lanthanide amide (Me4C5-SiMe2-NC4H4) YbN-(SiMe3)(2) (2), (2), in which the Yb atom is eta(5)-coordinated to both the C-5 and C4N rings. 2 rapidly reacted with dioxygen to give a dinuclear trivalent ytterbium species via intramolecular C-H and Si-N bond oxygenation reactions.

  DOI：

  10.1021/om9004127
• 作为产物：
  描述：

  bis[N,N-bistrimethylsilylamido]bis(tetrahydrofuran)ytterbium(II) 、 以 甲苯 为溶剂， 以65.2%的产率得到
  参考文献：
  名称：

  C−H and Si−N Bond Oxygenations of a Divalent Ytterbium Amide of the Pyrrolyl-Cyclopentadienyl Ligand

  摘要：

  Reaction of Me4C5H-SiMe2-NC4H4 with Yb[N-(SiMe3)(2)](2)(THF)(2) yielded a new type of ansa-sandwich divalent lanthanide amide (Me4C5-SiMe2-NC4H4) YbN-(SiMe3)(2) (2), (2), in which the Yb atom is eta(5)-coordinated to both the C-5 and C4N rings. 2 rapidly reacted with dioxygen to give a dinuclear trivalent ytterbium species via intramolecular C-H and Si-N bond oxygenation reactions.

  DOI：

  10.1021/om9004127