| 666720-36-1

• CAS: 666720-36-1
• 化学式: C₂₅H₂₆CoO₂*Cl
• 分子量: 452.926
• InChiKey: LCFBSCVJGJCNET-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (η5-C5Me5)Co(η4-fluorenone) 、 乙酰氯 以 二氯甲烷-D2 为溶剂， 生成
  参考文献：
  名称：

  Cyclopentadienone-like Behavior of Fluorenone and 4,5-Diazafluoren-9-one

  摘要：

  The aromatic compounds fluorenone (1) and 4,5-diazafluoren-9-one (2) behave like cyclopentadienones in their reaction with [Cp*Co(C2H4)(2)] (3a), affording the sandwich-type complexes [Cp*Co(eta(4)-1)] (4) and [Cp*Co(eta(4)-2)] (5), respectively, whose structures have been determined by X-ray diffraction. Both complexes show double-bond fixation in their eta(2)-coordinated six-membered rings and belong to a new structure type of mononuclear organometallics. The cobalt-coordinated ligands 1 and 2 present in 4 and 5, respectively, may be replaced by two molecules of carbon monoxide. In accord with their cyclopentadienone-like nature, they are nucleophilic and undergo O-acylation with acetyl chloride, affording cobaltocenium species.

  DOI：

  10.1021/om030615f