| 207740-60-1

• CAS: 207740-60-1
• 化学式: C₂₅H₃₈Cl₂OTi
• 分子量: 473.362
• InChiKey: SWVCGGCSGIFJAH-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  lithium 2,6-diisopropylphenolate 、 Ti(1,3-(t)-Bu2C5H3)Cl3 以 乙醚 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of Various Nonbridged Titanium(IV) Cyclopentadienyl−Aryloxy Complexes of the Type CpTi(OAr)X₂ and Their Use in the Catalysis of Alkene Polymerization. Important Roles of Substituents on both Aryloxy and Cyclopentadienyl Groups

  摘要：

  Various titanium complexes of the type Cp'Ti(OAr)Cl-2 (Cp' = cyclopentadienyl; OAr = aryloxy) could be prepared in high yields from Cp'TiCl3. These complexes show remarkable catalytic activities for alkene polymerization with MAO or (AlBu3)-Bu-i-Ph3CB(C6F5)(4): (C-5-Me-5)Ti(O-2,6-(Pr2C6H3)-Pr-i)X-2 (X = Cl (2b), Me (8b), CF3-SO3 (9b)) showed the highest activities. The bond angle Ti-O-C (phenyl group) in 2b (173.0 degrees) is significantly different from those for other complexes (162.3-163.1 degrees).

  DOI：

  10.1021/om980106r