2,2'-Dihydroperoxy-2,2'-diisopentylperoxid | 33372-83-7

• 英文名称: 2,2'-Dihydroperoxy-2,2'-diisopentylperoxid
• 英文别名: 1,4-diisopropyl-1,4-dimethyl-2,3-dioxa-butane-1,4-diyl bis-hydroperoxide；1,2,1',2'-tetramethyl-1,1'-peroxy-dipropyl bis-hydroperoxide；Hydroperoxide, 1,1'-[dioxybis(1,2-dimethylpropylidene)]bis-；2-hydroperoxy-2-(2-hydroperoxy-3-methylbutan-2-yl)peroxy-3-methylbutane
• CAS: 33372-83-7
• 化学式: C₁₀H₂₂O₆
• 分子量: 238.281
• InChiKey: MVNFSNOKNVAGBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  77.4
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3-甲基-2-丁酮 在 mineral acid 双氧水 作用下， 生成 2,2-dihydroperoxy-3-methylbutane 、 2,2'-Dihydroperoxy-2,2'-diisopentylperoxid
  参考文献：
  名称：

  EP1219602

  摘要：

  公开号：

文献信息

• Novel proton type beta zeolite, preparation method thereof and process for preparing phenol compound using the same
  申请人：UBE INDUSTRIES, LTD.

  公开号：US20040242938A1

  公开（公告）日：2004-12-02

  Disclosed are a proton type &bgr; zeolite in which an acid site showing a desorption peak with a range of ±100° C. with a center of 330° C. exists in a spectrum measured by the ammonia temperature programmed desorption method (NH 3 -TPD), and an amount of a strong acid site showing a desorption peak of 500° C. or higher is controlled to 2.5 &mgr;mol/g or less, a method for preparing the same, and a process for preparing a phenol compound by oxidizing a benzene compound with a peroxide in the presence of the proton type &bgr; zeolite.

  揭示了一种质子型β沸石，其中通过氨温度程序脱附法（NH3-TPD）测量的光谱中存在一个酸位显示出一个±100°C范围内的脱附峰，中心温度为330°C，并且控制强酸位显示出500°C或更高脱附峰的量为2.5μmol/g或更低，以及制备该沸石的方法和在质子型β沸石存在的情况下，在过氧化物存在下氧化苯化合物制备苯酚化合物的方法。
• Process and apparatus for producing dihydric phenolic compound
  申请人：Ube Industries, Ltd.

  公开号：EP0962439A1

  公开（公告）日：1999-12-08

  A dihydric phenolic compound is produced, with a high selectivity thereof, by a plurality of oxidation reactors connected to each other in series, by (1) feeding a monohydric phenolic compound with a temperature of 30 to 100°C, a peroxide compound, a catalyst and optionally a ketone compound into a first reactor to oxidize the monohydric phenolic compound, and delivering a resultant reaction mixture containing the produced dihydric phenolic compound and non-reacted monohydric phenolic compound from the first reactor; (2) passing the reaction mixture through one or more reactors succeeding to the first reactor, to further oxidize the monohydric phenolic compound, while, in the steps (1) and (2), a portion of the peroxide compound is fed into the first reactor and the remaining portion of the peroxide compound is fed into at least one succeeding reactor; and (3) delivering a first reaction mixture produced in a rearend reactor and comprising the produced dihydric phenolic compound, the non-reacted monohydric phenolic compound and peroxide compound and the catalyst from the rearend reactor.

  (1) 将温度为 30-100°C 的一水酚类化合物、过氧化物、催化剂和可选的酮类化合物送入第一反应器以氧化一水酚类化合物，并从第一反应器送出含有已生成的二水酚类化合物和未反应的一水酚类化合物的反应混合物，从而生产出具有高选择性的二水酚类化合物；(2) 将反应混合物通过第一反应器的一个或多个后续反应器，以进一步氧化一水酚类化合物，同时，在步骤 (1) 和 (2) 中，一部分过氧化物化合物被送入第一反应器，其余部分过氧化物化合物被送入至少一个后续反应器；(3) 将在后级反应器中产生的第一反应混合物从后级反应器中输送出来，该混合物包括产生的二水酚化合物、未反应的一水酚化合物和过氧化物化合物以及催化剂。
• Methyl isopropyl ketone peroxide formulations and their use for curing unsaturated polyesters
  申请人：Akzo Nobel N.V.

  公开号：EP1219602A1

  公开（公告）日：2002-07-03

  Methyl propyl ketone peroxide formulations are claimed that can be safely handled at ambient temperature, are storage stable, and give fast curing rates of unsaturated polyester resins particularly when accelerated with a complex of two different metals. The claimed products are particularly suited for thin articles and coating such as suited for use in gel coat systems. The pure ketone peroxides consist of more than 60% by weight of type-4 methyl propyl ketone peroxide and used as formulations containing sufficient amount of a non-aqueous phlegmatizer.

  过氧化甲基丙基酮配方可在环境温度下安全处理，储存稳定，并能快速固化不饱和聚酯树脂，特别是在使用两种不同金属的复合物加速固化时。所声称的产品特别适用于薄制品和涂层，例如适用于胶衣系统。纯酮过氧化物由重量百分比超过 60% 的 4 型甲基丙基酮过氧化物组成，用作含有足量非水性化痰剂的配方。
• THERMOPLASTIC ELASTOMER COMPOSITION AND METHOD FOR PRODUCING SAME
  申请人：JSR Corporation

  公开号：EP1816163A1

  公开（公告）日：2007-08-08

  A thermoplastic elastomer composition obtained by dynamically heat-treating a mixture containing a thermoplastic resin (A) having a melting point of not less than 200°C and an elastomer (B) having a constitutional unit derived from an ester group-containing monomer in the presence of, as a crosslinking agent (C), a polymer (C-1) comprising a (meth)acrylate (c-1) unit having a weight average molecular weight (Mw) of 1,000 to 30,000 and a molecular weight distribution (Mw/Mn) of 1.0 to 4.0 and/or a polymer (C-2) which comprises 5 to 35 mass% of the (meth)acrylate (c-1) unit and 65 to 95 mass% of an aromatic vinyl monomer (c-2) unit, the polymer (C-2) having a weight average molecular weight (Mw) of 1,000 to 30,000 and a molecular weight distribution (Mw/Mn) of 1.0 to 4.0. The composition has a good sea-island structure as a whole and excellent cold resistance, and is useful as a substitute for acrylic rubbers.

  一种热塑性弹性体组合物，通过动态热处理含有熔点不低于 200°C 的热塑性树脂 (A) 和弹性体 (B) 的混合物而获得，弹性体 (B) 的结构单元来自含酯基的单体，作为交联剂 (C)，聚合物 (C-1) 包括(甲基)丙烯酸酯 (c-1)单元，其重量平均分子量 (Mw) 在 1,000 至 30,000 之间，分子量分布 (Mw/Mn) 在 1.0 至 4.0 之间，和/或聚合物 (C-2)，其包括 5 至 35 质量％的(甲基)丙烯酸酯 (c-1) 单元和 65 至 95 质量％的芳香族乙烯基单体 (c-1)。该聚合物（C-2）具有 1,000 至 30,000 的重量平均分子量（Mw）和 1.0 至 4.0 的分子量分布（Mw/Mn）。该组合物具有良好的整体海岛结构和优异的耐寒性，可用作丙烯酸橡胶的替代品。
• Accelerator for curing resins
  申请人：Akzo Nobel Chemicals International B.V.

  公开号：EP2626383A1

  公开（公告）日：2013-08-14

  Accelerator formulation suitable for accelerating resin cure, comprising (i) an organic manganese compound, (ii) an oxime, (iii) a phosphate ester, and (iv) an amino alcohol.

  适用于加速树脂固化的促进剂配方，包括 (i) 有机锰化合物、(ii) 肟、(iii) 磷酸酯和 (iv) 氨基醇。