dichloro[1,3-bis(2-benzimidazolylimino)isoindoline]manganese(II) | 1227311-17-2

• 英文名称: dichloro[1,3-bis(2-benzimidazolylimino)isoindoline]manganese(II)
• 英文别名: [Mn(1,3-bis(2-benzimidazolylimino)isoindoline)Cl2]
• CAS: 1227311-17-2
• 化学式: C₂₂H₁₅Cl₂MnN₇
• 分子量: 503.252
• InChiKey: HNJPVIPQRPFXHH-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 1,3-bis-(2′-benzimidazolylimino)isoindoline 以 甲醇 、 乙腈 为溶剂， 以85%的产率得到dichloro[1,3-bis(2-benzimidazolylimino)isoindoline]manganese(II)
  参考文献：
  名称：

  Synthesis, structure, and catalase-like activity of a novel manganese(II) complex: Dichloro[1,3-bis(2′-benzimidazolylimino)isoindoline]manganese(II)

  摘要：

  Reaction of the ligand 1,3-bis(2'-benzimidazolylimino)isoindoline with manganese(II) chloride in acetonitrile/methanol leads to the novel mononuclear manganese(II) complex 1,3-bis(2'-benzimidazolylimino)isoindolinedichloro manganese(II) [Mn(bimindH)Cl-2], which has been characterized by various techniques such as elemental analysis, IR, UV-Vis, ESR spectroscopy. and X-ray diffraction. The ligand bimindH was synthesized by fusing phthalonitrile and 2-aminobenzimidazole at high temperature until ammonia evolution ceased. The catalase-like activity of the complex was tested in propionitrile, and it proved to be active in the dihydrogen peroxide dismutation. Based on kinetic studies the reaction is first-order in relation to both the complex and hydrogen peroxide. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.01.008
• 作为试剂：
  描述：

  双氧水 在 dichloro[1,3-bis(2-benzimidazolylimino)isoindoline]manganese(II) 作用下， 以 further solvent(s) 为溶剂， 生成 水 、 氧气
  参考文献：
  名称：

  Synthesis, structure, and catalase-like activity of a novel manganese(II) complex: Dichloro[1,3-bis(2′-benzimidazolylimino)isoindoline]manganese(II)

  摘要：

  Reaction of the ligand 1,3-bis(2'-benzimidazolylimino)isoindoline with manganese(II) chloride in acetonitrile/methanol leads to the novel mononuclear manganese(II) complex 1,3-bis(2'-benzimidazolylimino)isoindolinedichloro manganese(II) [Mn(bimindH)Cl-2], which has been characterized by various techniques such as elemental analysis, IR, UV-Vis, ESR spectroscopy. and X-ray diffraction. The ligand bimindH was synthesized by fusing phthalonitrile and 2-aminobenzimidazole at high temperature until ammonia evolution ceased. The catalase-like activity of the complex was tested in propionitrile, and it proved to be active in the dihydrogen peroxide dismutation. Based on kinetic studies the reaction is first-order in relation to both the complex and hydrogen peroxide. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.01.008