[Cu(N-(2-pyridylethyl)pyridine-2-carbaldimine)Br]PF6 | 144391-42-4

• 英文名称: [Cu(N-(2-pyridylethyl)pyridine-2-carbaldimine)Br]PF6
• CAS: 144391-42-4
• 化学式: Br*C₁₃H₁₃N₃*Cu*F₆P
• 分子量: 499.68
• InChiKey: JMQQUUXHEKCJHN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 以 甲醇 为溶剂， 生成 [Cu(N-(2-pyridylethyl)pyridine-2-carbaldimine)Br]PF6
  参考文献：
  名称：

  Unusual magnetic chain of copper(II) ions in [Cu(pepci)Br]_n-[PF₆]_n[pepci =N-(2-pyridylethyl)pyridine-2-carbaldimine]

  摘要：

  The complex [Cu(pepci)Br]PF6 [pepci = N-(2-pyridylethyl)pyridine-2-carbaldimine] has been synthesised and characterization by X-ray crystallography shows it to contain cationic mono-mu-bromocopper(II) chains, with two crystallographically independent consecutive cations forming -Cu(pepci)-Br-Cu(pepci)-Br-units which repeat by translation to give the chain structure, and isolated PF6- counter ions; the ESR spectrum, showing the forbidden DELTA-M(s) = 2 transition, is indicative of interactions between copper(II) pairs, and the preliminary magnetic susceptibility data indicate a weak antiferromagnetic behaviour.

  DOI：

  10.1039/dt9920002125

文献信息

• Cortés, Roberto; Lezama, Luis; Ruiz De Larramendi, Inorganic Chemistry, 1995, vol. 34, # 4, p. 778 - 786
  作者：Cortés, Roberto、Lezama, Luis、Ruiz De Larramendi、Madariaga, Gotzon、Mesa, J. Luis、Zuñiga, F. Javier、Rojo, Teófilo

  DOI：——

  日期：——